Norbornene dicarboxylic anhydride. 5 2022-12-12

Norbornene dicarboxylic anhydride Rating: 4,8/10 572 reviews

Norbornene dicarboxylic anhydride (NDCA) is a chemical compound that belongs to the class of organic compounds known as norbornenes. It is a cyclic compound with a seven-membered ring structure and is composed of two carboxylic acid groups and an anhydride group. NDCA is a white solid at room temperature and has a melting point of around 174°C.

NDCA is synthesized through the dehydration of a dicarboxylic acid, such as maleic acid, using a strong acid catalyst. It can also be synthesized through the Diels-Alder reaction between norbornadiene and maleic anhydride. The resulting product is a mixture of isomers, including cis- and trans-NDCA.

NDCA has a number of important industrial applications. It is used as a monomer in the synthesis of polymers, such as polyamides and polyimides, which have a wide range of applications including coatings, adhesives, and fibers. NDCA is also used in the production of resins, plasticizers, and rubber additives.

In addition to its use in the polymer industry, NDCA has also been studied for its potential use in the pharmaceutical industry. It has been shown to have anti-inflammatory and analgesic properties, and it has been suggested that it may have potential as a drug for the treatment of pain and inflammation.

Despite its potential benefits, NDCA also has some potential drawbacks. It is a known irritant to the skin and eyes, and it may also be harmful if ingested or inhaled. Therefore, it is important to handle NDCA with caution and to use appropriate protective equipment when working with it.

In conclusion, norbornene dicarboxylic anhydride is a versatile chemical compound with a number of important industrial and potential pharmaceutical applications. However, it is important to handle it with caution due to its potential irritant and harmful effects.

Synthesis of Cis

norbornene dicarboxylic anhydride

The anhydride groups may be reacted with monohydric alcohols to produce monoester acids or diesters, depending upon the relative amount of alcohol and the reaction conditions. Download any file posted by another user of a Community Feature that you know, or reasonably should know, cannot be legally distributed in such manner or that you have a contractual obligation to keep confidential notwithstanding its availability on the Web Site. You agree that any action at law or in equity that arises out of or relates to these Terms and Conditions of Use will be filed exclusively in the state or federal courts located in Pennsylvania and you hereby consent and submit to the personal jurisdiction of such courts for the purposes of litigating any such action. It is utilized in the flame retarding treatment. IF IN EYES: Rinse cautiously with water for several minutes.

Next

5

norbornene dicarboxylic anhydride

The novel polymers of this invention may be converted into numerous derivatives by any of the known reactions for organic compounds containing anhydride groups. Photoresist monomer having hydroxy group and carboxy group, copolymer thereof and photoresist composition using the same US6586619B2 en 1998-08-26 2003-07-01 Hyundai Electronics Industries Co. Excludes regulated items and items that ship on ice. Violate any applicable laws or regulations or violate any code of conduct or other guidelines which may be applicable for any particular Community Feature. However, the absorption peak at 6.

Next

Methyl

norbornene dicarboxylic anhydride

P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Diels- Alder reactions are used constantly in the medical field due to its diverse uses. Integration of the NMR absorption peaks confirmed the equimolar composition of the copolymer. These Terms and Conditions of Use are applicable to users in the United States, Canada, and Puerto Rico. This reaction is so important because of its ability to form new carbon-carbon bonds.


Next

cis

norbornene dicarboxylic anhydride

May cause an allergic skin reaction. Synthesis of polymer-supported TEMPO catalysts and their application in the oxidation of various alcohols. Assignors: GE CHEMICALS, INC. However, the Company can neither review all material before it is posted on the Web Site nor ensure prompt removal of objectionable material after it has been posted. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. The yield of dioxane-insoluble copolymer was 0. The copolymer had a softening point of 255°-260° C.

Next

129

norbornene dicarboxylic anhydride

Do NOT induce vomiting P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. The NMR spectrum of the copolymer in acetone-d 6 at room temperature showed absorption in the 5. P285 : In case of inadequate ventilation wear respiratory protection. We may terminate your access, or suspend any user's access to all or part of the Site, without notice, for any conduct that we, in our sole discretion, believe is in violation of any applicable law or is harmful to the interests of another user, a third-party provider, a service provider, or us. The NMR spectrum contained peaks centered at 6.

Next

cis

norbornene dicarboxylic anhydride

Misrepresent an affiliation with any person or organization. Conclusion: The Diels- Alder reaction is one of the most important types of reactions in organic chemistry Weldegirma, 2012. When either isomer is heated at a sufficiently elevated temperature, isomerization occurs and a mixture of both isomers is obtained. This type of reaction was named for Otto Diels and Kurt Alder who were the first to investigate this reaction Weldegirma, 2012. The anhydride groups may also be reacted with amines to yield monoamide acids or diamides or imides and with ammonium hydroxide to produce the mono-or diammonium salts as well as the monoamide-monoammonium salt. I believe that we did accomplish what we set out to do in this lab.

Next

cis

norbornene dicarboxylic anhydride

Clay catalysis: A convenient and rapid formation of anhydride from carboxylic acid and isopropenyl acetate under microwave irradiation. Our failure to exercise or enforce any right or provision of the Terms and Conditions of Use shall not constitute a waiver of such right or provision. The support you need to optimize operations Avantor Services provides a wide range of specialized services and digital solutions to help you solve complex challenges. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Copolymer resin, preparation thereof, and photoresist using the same US6369181B1 en 1997-12-29 2002-04-09 Hyundai Electronics Industries Co.

Next

Influence of norbornene dicarboxylic anhydride on the copolymerization of carbon dioxide and propylene oxide

norbornene dicarboxylic anhydride

The free radical precursor is used in catalytic quantities, e. Harvest or otherwise collect information about others, including e-mail addresses, without their consent. A process for the preparation of terpolymers of maleic anhydride and the exo and endo cyclic adducts of maleic anhydride and a cyclic conjugated diene, said diene selected from the group consisting of cyclopentadiene and methylcyclopentadiene, which comprises heating maleic anhydride and either cyclic adduct in the presence of a free radical precursor, at a reaction temperature which is a temperature of endo-exo isomerization of the adduct. If you choose to follow any such recommendation you do so at your own risk. P363 : Wash contaminated clothing before reuse. The Diels-Alder adduct from cyclopentadiene and maleic anhydride, endo-cis-5-norbornene-2, 3-dicarboxylic anhydride, m. We have become experts in scientific operations, improving performance with sophisticated solutions and providing guidance on best practices.

Next